Skip to main navigation menu Skip to main content Skip to site footer

SECTION C: ENGINEERING

Vol. 7 No. 2 (2015)

Relationships Process, Microstructure, Properties of Hard Chromium Plating in Laboratory Scale

DOI
https://doi.org/10.18272/aci.v7i2.268
Submitted
January 22, 2016
Published
2015-12-30

Abstract

In this work hard chromium electroplating process is developed on small test specimens on AISIA36 steel. This paper includes the development of hard chrome plating process at laboratory scale and provide a simplified procedure for industrial applications. By applying a differential power over the A36 steel submerged in an electrolytic bath of chromic acid, a thin coat of 30 to 80 microns of chrome is deposited over the specimen. The hard chrome deposition is achieved by a combination of multiple variables such as: chromic acid concentration, substrate metal, anodes, current density, solution temperature and time. From the abovementioned parameters, the time and the current density are the working parameters to be manipulated while the others remain unchanged. For these experiment, a linear simplified model is theoretically and experimentally derived from Faraday’s electro-deposition law for hard chrome plating. The thickness variation, micro-hardness and cracking network of the combination of the working parameters are included and discussed in this work. The chrome deposit obtained is microscopically and gravimetrically measured. The results obtained by combining the working parameters show hardness values within the range provided of 66 to 70 HRC. This paper studies and analyzes the possible causes that influence hardness with the microstructure (number of surface cracks, density) and processing parameters such as time and current density.

viewed = 1297 times

References

  1. Kostylev, A.; Pokrovsky, Y.; Lumpov, A. 2012. "Advanced Chromium Carbide Coatings on Piston Rings by CVD: A Highly Adaptable new method with relatively low cost". Cengage Learning: 2-26.
  2. American Society for Metals. 1994. "Handbook of Surface Engineering". ASM International.
  3. Birnbaum, H. K. 1986. "Hydrogen Embrittlement". Pergamon Press.
  4. U.S. Environmental Protection Agency. 1998. "Toxicological Review of Hexavalent Chromium". Washington, DC., United States: National Center for Environmental Assessment, Office of Research and Development.
  5. Jewett, R. P.; Walter, R. J.; Chandler, W. T.; Frohmberg, R. P. 1973. "Hydrogen environment embrittlement of metals". Canoga Park, CA: NASA United States.
  6. Ellor, J.; Young, W. 2004. "Thermally Sprayed Metal Coatings to Protect Steel Pilings: Final Report and Guide". Washington DC: Transportation Research Board (528).
  7. Industria Metalquímica Galvano. 2011. "Boletín técnico Sistema de Cromo Di-Co". Quito: 1-2.
  8. American Society for Testing and Materials. 2005. "Guide for Preparation of Metallographic Specimens" ASTME3-01: 1-12.
  9. American Society for Testing and Materials. 2005. "Practice for Microetching Metals and Alloys". ASTM E407: 1-21.
  10. Such, T. E.; Dennis, J. K. 1993. "Nickel and Chromium Plating", Third Edition ed. Ohio, United States: Woodhead Publishing Ltd & ASM International.
  11. American Society for Testing and Materials. 2005. "Standard Test Method for Microindentation Hardness of Materials". ASTM E384: 1-24.