Design of a lignocellulosic waste conversion route for the production of butane as a substitute for liquefied petroleum gas
PDF (Spanish)
HTML (Spanish)
XML (Spanish)

Keywords

BioLPG
Butane
Biofuels
Fermentation
Banana pseudostem
Lignocellulose

Categories

How to Cite

Orozco Fuentes, D. S. ., Velastegui Nuñez, A. P. ., & Vela-Garcia, N. (2023). Design of a lignocellulosic waste conversion route for the production of butane as a substitute for liquefied petroleum gas. ACI Avances En Ciencias E Ingenierías, 15(1), 21. https://doi.org/10.18272/aci.v15i1.2884

Abstract

Liquefied petroleum gas (LPG) is essential, mainly for domestic use, representing 10.4% of Ecuador's energy demand. In the absence of mechanisms for the valorization of lignocellulosic waste in the country, a biomass-to-butane conversion route was proposed as a substitute for LPG through a computational design to evaluate its technical, economic and environmental feasibility. The optimal waste for the process was selected based on the annual generation rate and physical-chemical composition. The route configuration was designed in AspenPlus® with an input of 77 t/h biomass. Based on the results, an economic and life cycle analysis was carried out using the openLCA® software. Butane production reached seven tons per hour and an energy density of 26.7 MJ/L.

Regarding the economic axis, the minimum sale price calculated was $1.03/kg, considering the sale of lignin as a co-product. In this way, the biofuel was competitive with the sale price of one dollar per kilogram of LPG. Finally, the total carbon footprint of the process was 102 g CO2-eq/MJ, higher than the European standard of 94 g CO2-eq/MJ. This research opens the door towards optimizing resources and transforming the country's energy matrix.

PDF (Spanish)
HTML (Spanish)
XML (Spanish)

References

Ryskamp, R. (2017). Emissions and Performance of Liquefied Petroleum Gas as a Transportation Fuel: A Review. Recuperado de https://auto-gas.net/wp-content/uploads/2019/11/2017-WLPGA-Literature-Review.pdf

Troncoso, K., & Soares, A. (2017). LPG fuel subsidies in Latin America and the use of solid fuels to cook. Energy Policy, 107(January), 188–196. https://doi.org/10.1016/j.enpol.2017.04.046

WLPGA, & Argus. (n/f). Latin America 2020 WLPGA.

Ministerio de Energía y Minas. (2021a). Balance Energético Nacional 2021.

Banco Central del Ecuador. (2012). Reporte Del Sector Petrolero. In Banco Central del Ecuador. Recuperado de https://contenido.bce.fin.ec/documentos/Estadisticas/Hidrocarburos/ASP201606.pdf

Banco Central del Ecuador. (n/f). Informe de la evolución de la economía ecuatoriana en 2021 y perspectivas 2022. Recuperado de https://contenido.bce.fin.ec/documentos/Administracion/EvolEconEcu_2021pers2022.pdf

Márquez, J. (2021). Boletin Técnico: Encuesta de Superficie y Producción Agropecuaria Continua, 2020. Recuperado de https://www.ecuadorencifras.gob.ec/documentos/web-inec/Estadisticas_agropecuarias/espac/espac-2020/Boletin%20Tecnico%20ESPAC%202020.pdf

Loor, M. C., Andrade, F., Lizarzaburu, L., & Masache, M. (2017). Valoración económica de los cobeneficios del aprovechamiento energético de los residuos agrícolas en el Ecuador. Recuperado de https://www.cepal.org/es/publicaciones/41830-valoracion-economica-cobeneficios-aprovechamiento-energetico-residuos-agricolas

Ballesteros-González, K., Sullivan, A. P., & Morales-Betancourt, R. (2020). Estimating the air quality and health impacts of biomass burning in northern South America using a chemical transport model. Science of the Total Environment, 739. https://doi.org/10.1016/j.scitotenv.2020.139755

Singh, R., Das, R., Sangwan, S., Rohatgi, B., Khanam, R., Peera, S. K. P. G., Das, S., Lyngdoh, Y. A., Langyan, S., Shukla, A., Shrivastava, M., & Misra, S. (2021). Utilisation of agro-industrial waste for sustainable green production: a review. Environmental Sustainability, 4(4), 619–636. https://doi.org/10.1007/s42398-021-00200-x

The Global LPG Partnership. (2020). Assessing Potential for BioLPG Production and Use within the Cooking Energy Sector in Africa. Global LPG Partnership, September. Recuperado de https://mecs.org.uk/wp-content/uploads/2020/09/GLPGP-Potential-for-BioLPG-Production-and-Use-as-Clean-Cooking-Energy-in-Africa-2020.pdf

Johnson, E. (2019a). Process technologies and projects for BiOLPG. In Energies (Vol. 12, Issue 2). MDPI AG. https://doi.org/10.3390/en12020250

Teimouri, Z., Abatzoglou, N., & Dalai, A. K. (2021). Kinetics and selectivity study of fischer-tropsch synthesis to c5+ hydrocarbons: A review. Catalysts, 11(3), 19–31. https://doi.org/10.3390/catal11030330

Kan, T., Strezov, V., Evans, T., He, J., Kumar, R., & Lu, Q. (2020). Catalytic pyrolysis of lignocellulosic biomass: A review of variations in process factors and system structure. In Renewable and Sustainable Energy Reviews (Vol. 134). Elsevier Ltd. https://doi.org/10.1016/j.rser.2020.110305

Costa, M., Piazzullo, D., Di, D., & Vita, A. De. (2022). Sustainability assessment of the whole biomass-to-energy chain of a combined heat and power plant based on biomass gasification : biomass supply chain management and life cycle assessment. Journal of Environmental Management, 317, 115434. https://doi.org/10.1016/j.jenvman.2022.115434

Vela-garcía, N., Bolonio, D., García-martínez, M., Ortega, M. F., Almeida, D., & Canoira, L. (2021). Biojet fuel production from oleaginous crop residues : thermoeconomic , life cycle and flight performance analysis. Energy Conversion and Management, 244, 114534. https://doi.org/10.1016/j.enconman.2021.114534

Onwudili, J. A., & Nouwe Edou, D. J. (2022). Process modelling and economic evaluation of biopropane production from aqueous butyric acid feedstock. Renewable Energy, 184, 80–90. https://doi.org/10.1016/j.renene.2021.11.043

Retto-Hernandez, P., Rojas, M. L., Lescano, L., Sanchez-Gonzalez, J., & Linares, G. (2020a). Lignocellulosic agroindustrial waste in Peru: Potential for bioethanol, energy, and reduction of CO2 emission. Proceedings of the LACCEI International Multi-Conference for Engineering, Education and Technology. https://doi.org/10.18687/LACCEI2020.1.1.463

Vandenberghe, L. P. de S., Junior, N. L., Valladares-Diestra, K. K., Bittencourt, G. A., Murawski de Mello, A. F., Karp, S. G., Junior Letti, L. A., & Soccol, C. R. (2022). Nonwaste technology in the bioethanol and biodiesel industries. Biofuels and Bioenergy, 41–60. https://doi.org/10.1016/B978-0-323-85269-2.00019-8

Arce, C., & Kratky, L. (2022). Mechanical pretreatment of lignocellulosic biomass toward enzymatic/fermentative valorization. IScience, 25(104610), 1–8. https://doi.org/10.1016/j.isci

Shimizu, F. L., Monteiro, P. Q., Ghiraldi, P. H. C., Melati, R. B., Pagnocca, F. C., Souza, W. de, Sant’Anna, C., & Brienzo, M. (2018). Acid, alkali and peroxide pretreatments increase the cellulose accessibility and glucose yield of banana pseudostem. Industrial Crops and Products, 115, 62–68. https://doi.org/10.1016/j.indcrop.2018.02.024

Pfromm, P. (2008). The Minimum Water Consumption of Ethanol Production via Biomass Fermentation. The Open Chemical Engineering Journal, 2(2). DOI: 10.2174/1874123100802010001

de Souza, E. L., Sellin, N., Marangoni, C., & Souza, O. (2017). The Influence of Different Strategies for the Saccharification of the Banana Plant Pseudostem and the Detoxification of Concentrated Broth on Bioethanol Production. Applied Biochemistry and Biotechnology, 183(3), 943–965. https://doi.org/10.1007/s12010-017-2475-7

Souza, E. L., Liebl, G. F., Marangoni, C., Sellin, N., Montagnoli, M. S., & Souza, O. (2014). Bioethanol from fresh and dried banana plant pseudostem. Chemical Engineering Transactions, 38, 271–276. https://doi.org/10.3303/CET1438046

Shoji, T., Kawamoto, H., & Saka, S. (2014). Boiling point of levoglucosan and devolatilization temperatures in cellulose pyrolysis measured at different heating area temperatures. Journal of Analytical and Applied Pyrolysis, 109, 185–195. https://doi.org/10.1016/j.jaap.2014.06.014

Wang, J., Shen, X., Lin, Y., Chen, Z., Yang, Y., Yuan, Q., & Yan, Y. (2018). Investigation of the Synergetic Effect of Xylose Metabolic Pathways on the Production of Glutaric Acid. ACS Synthetic Biology, 7(1), 24–29. https://doi.org/10.1021/acssynbio.7b00271

Moysés, D. N., Reis, V. C. B., de Almeida, J. R. M., de Moraes, L. M. P., & Torres, F. A. G. (2016). Xylose fermentation by saccharomyces cerevisiae: Challenges and prospects. In International Journal of Molecular Sciences, 17(3). MDPI AG. https://doi.org/10.3390/ijms17030207

Nosrati-Ghods, N., Harrison, S. T. L., Isafiade, A. J., & Tai, S. L. (2020). Analysis of ethanol production from xylose using Pichia stipitis in microaerobic conditions through experimental observations and kinetic modelling. Biochemical Engineering Journal, 164. https://doi.org/10.1016/j.bej.2020.107754

Silva, J. P. A., Mussatto, S. I., Roberto, I. C., & Teixeira, J. A. (2011). Ethanol production from xylose by Pichia stipitis NRRL Y-7124 in a stirred tank biorreactor. Brazilian Journal of Chemical Engineering, 28(1), 151–156. www.abeq.org.br/bjche

Gil, I. D., Uyazán, A. M., Aguilar, J. L., Rodríguez, G., & Caicedo, L. A. (2008). SEPARATION OF ETHANOL AND WATER BY EXTRACTIVE DISTILLATION WITH SALT AND SOLVENT AS ENTRAINER: PROCESS SIMULATION. Brazilian Journal of Chemical Engineering, 25(01), 207–215. https://doi.org/10.1590/S0104-66322008000100021

Junqueira, T. L., Filho, R. M., & Maciel, M. R. W. (2009). Simulation of distillation process in the bioethanol production using nonequilibrium stage model. In Computer Aided Chemical Engineering 27(C). Elsevier Inc. https://doi.org/10.1016/S1570-7946(09)70343-8

Li, G., & Bai, P. (2012). New operation strategy for separation of ethanol-water by extractive distillation. Industrial and Engineering Chemistry Research, 51(6), 2723–2729. https://doi.org/10.1021/ie2026579

Frosi, M., Tripodi, A., Conte, F., Ramis, G., Mahinpey, N., & Rossetti, I. (2021a). Ethylene from renewable ethanol: Process optimization and economic feasibility assessment. Journal of Industrial and Engineering Chemistry, 104, 272–285. https://doi.org/10.1016/j.jiec.2021.08.026

Becerra, J., Quiroga, E., Tello, E., Figueredo, M., & Cobo, M. (2018). Kinetic modeling of polymer-grade ethylene production by diluted ethanol dehydration over H-ZSM-5 for industrial design. Journal of Environmental Chemical Engineering, 6(5), 6165–6174. https://doi.org/10.1016/j.jece.2018.09.035

ACS Material. (n/f). Technical Data Sheet Series Zeolite Powder. Recuperado de https://www.acsmaterial.com/zsm-5-series-zeolite-powder.html

Frosi, M., Tripodi, A., Conte, F., Ramis, G., Mahinpey, N., & Rossetti, I. (2021b). Ethylene from renewable ethanol: Process optimization and economic feasibility assessment. Journal of Industrial and Engineering Chemistry, 104, 272–285. https://doi.org/10.1016/j.jiec.2021.08.026

Al-Faze, R., Kozhevnikova, E. F., & Kozhevnikov, I. v. (2021). Diethyl Ether Conversion to Ethene and Ethanol Catalyzed by Heteropoly Acids. ACS Omega, 6(13), 9310–9318. https://doi.org/10.1021/acsomega.1c00958

Palomino Infante, A. (2004). Análisis Pinch y su contribución a la integración de procesos. Revista de la Sociedad Química del Perú, 70(3), 167–174. Recuperado de https://sisbib.unmsm.edu.pe/bibvirtualdata/publicaciones/rsqp/n3_2004/a06.pdf

Rossi, C. (2021). Análisis PINCH: Herramienta práctica para la eficiencia térmica en procesos, reducción de costos e impacto ambiental. Recuperado de https://www.cecacier.org/wp-content/uploads/2021/07/Analisis-Pinch-24-6-2021-CRS.pdf

Mohammadzade Fard, S., Farsi, M., & Rahimpour, M. R. (2021). Optimization of ethylene dimerization in a bubble column reactor based on coupling kinetic and equilibrium models. Chemical Engineering Research and Design, 174, 357–364. https://doi.org/10.1016/j.cherd.2021.07.030

Belov, G. P. (2008). Selective dimerization, oligomerization, homopolymerization and copolymerization of olefins with complex organometallic catalysts. In Russian Journal of Applied Chemistry, 81(9), 1655–1666). https://doi.org/10.1134/S107042720809036X

Hamed, S., Soudbar, D., & Pavari, M. (2010). Selective Ethylene Dimerization Toward 1-butene by a New Highly Efficient Catalyst System and Determination of Its Optimum Operating Conditions in a Buchi Reactor. International Journal of Chemical Engineering and Applications, 1(3), 276–281. doi 10.7763/ijcea.2010.v1.48

Ristovic, M., & Pacolli, M. (2017). Oligomerization of Ethylene and Ethanol into Fuel Through Heterogeneous Catalysis. Lund University. Recuperado de https://lup.lub.lu.se/luur/download?func=downloadFile&recordOId=8916580&fileOId=8916582

Kwantlen Polytechnic University. (n/f). Reaction of Alkenes: Hydrogenation. Recuperado de https://kpu.pressbooks.pub/organicchemistry/chapter/10-5-reaction-of-alkenes-hydrogenation/#

Akchurin, T. I., Baibulatova, N. Z., Grabovskii, S. A., Talipova, P. P., Galkin, E. G., & Dokichev, V. A. (2016). Alkene hydrogenation over palladium supported on a carbon–silica material. Kinetics and Catalysis, 57(5), 586–591. https://doi.org/10.1134/S0023158416050025

Tianlong. (n/f). LPG Cylinder. Recuperado de https://www.alibaba.com/product-detail/Lpg- Cylinder-Hot-Quality-12-5kg_62455310881.html?spm=a2700.galleryofferlist.normal_offer.d_image.c96d26e099dlRc&s=p

Economic Indicators. (2014, marzo). Chemical Engineering. Recuperado de www.che.com/pci

Guthrie, K. M. (1969). Capital Cost Estimating. Chemical Engineering. 114-142.

Mignard, D. (2014). Correlating the chemical engineering plant cost index with macro-economic indicators. Chemical Engineering Research and Design, 92(2), 285–294. https://doi.org/10.1016/j.cherd.2013.07.022

Cheali, P., Gernaey, K. v., & Sin, G. (2015). Uncertainties in early-stage capital cost estimation of process design - A case study on biorefinery design. Frontiers in Energy Research, 3(FEB). https://doi.org/10.3389/fenrg.2015.00003

Office of Energy Efficiency & Renewable Energy. (n/f.). Bioenergy Career Grid. Recuperado de https://www.energy.gov/eere/bioenergy/bioenergy-career-grid

Zhang, Y., Goldberg, M., Tan, E., & Meyer, P. A. (2016). Estimation of economic impacts of cellulosic biofuel production: A comparative analysis of three biofuel pathways. Biofuels, Bioproducts and Biorefining, 10(3), 281–298. https://doi.org/10.1002/bbb.1637

Bureau of Labor Statistics. (2021). May 2021 OEWS Research Estimates. In Nursing Research 16(1). Recuperado de https://www.bls.gov/oes/2021/may/oes_research_estimates.htm

Vianey, J. (2018). Aportes teóricos sobre el flujo de caja. https://doi.org/10.13140/RG.2.2.29021.72166

Lindorfer, J., Rosenfeld, D., Annevelink, B., & Mandl, M. (2019, junio). Technical, Economic and Environmental Assessment of Biorefinery Concepts Developing a practical approach for characterization. IEA Bioenergy. Recuperado de https://www.ieabioenergy.com/blog/publications/new-publication-technical-economic-and-environmental-assessment-of-biorefinery-concepts-developing-a-practical-approach-for-characterisation/

GreenDelta. (2022). openLCA modeling suite. Recuperado de https://www.openlca.org/openlca/

Li, M., & Subramaniam, B. (2017). LCA for Green Chemical Synthesis Terephthalic Acid. Encyclopedia of Sustainable Technologies, 387–396. https://doi.org/10.1016/B978-0-12-409548-9.10086-7

Neves, T. I., Uyeda, C. A., Carvalho, M., & Abrahão, R. (2018). Environmental evaluation of the life cycle of elephant grass fertilization — Cenchrus purpureus (Schumach.) Morrone — using chemical fertilization and biosolids. https://doi.org/10.1007/s10661-017-6406-4

Estrella, L. H. (2021). Factor de emisión de CO2 del Sistema Nacional Interconectado - Informe 2020. 40. Recuperado de https://www.ambiente.gob.ec/wp-content/uploads/downloads/2020/11/factor_de_emision_de_co2_del_sistema_nacional_interconectado_de_ecuador_-_informe_2019.pdf

Mcallister, S., & Processes, C. (2011). Properties of Fuels. https://doi.org/10.1007/978-1-4419-7943-8

Johnson, E. (2019b). Process technologies and projects for BiOLPG. Energies 12(2). https://doi.org/10.3390/en12020250

Europe Liquid Gas. (2021). BIOLPG A Renewable Pathway towards 2050.

Hopwood, L., Mitchell, E., & Sourmelis, S. (2019). Biopropane: Feedstocks, Feasibility and our Future Pathway. Recuperado de www.nnfcc.co.uk

Suhag, M., Kumar, A., & Singh, J. (2020). Saccharification and fermentation of pretreated banana leaf waste for ethanol production. SN Applied Sciences, 2(8), 1–9. https://doi.org/10.1007/s42452-020-03215-x

Young, S., & Fortey, E. (1902). The Propierties of Mixtures of the Lower Alcohols with Benzene and with Benzene and Water. Journal of the Chemical Society, 81, 739–752. https://doi.org/10.1039/CT9028100739

IARC. (2017). IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISKS TO HUMANS: BENZENE. 120. Recuperado de https://publications.iarc.fr/Book-And-Report-Series/Iarc-Monographs-On-The-Identification-Of-Carcinogenic-Hazards-To-Humans/Benzene-2018

Koczka, K., Mizsey, P., & Fonyo, Z. (2007). Rigorous modelling and optimization of hybrid separation processes based on pervaporation. Central European Journal of Chemistry, 5(4), 1124–1147. https://doi.org/10.2478/s11532-007-0050-8

Eweremadu, C., & Rutto, H. (2010). Investigation of Heat Loss in Ethanol-Water Distillation Column with Direct Vapour Recompression Heat Pump. International Journal of Chemical and Molecular Engineering, 4(9), 548–549. scholar.waset.org/1307-6892/1577

Kiss, A. A., & Smith, R. (2020). Rethinking energy use in distillation processes for a more sustainable chemical industry. Energy, 203. https://doi.org/10.1016/j.energy.2020.117788

NETZSH. (2014). Thermal Insulation Materials. Analysing & Testing. www.netzsch.com

La Hora. (2021, agosto 04). El subsidio por tanque de gas supera los $13. La Hora. Recuperado de https://www.lahora.com.ec/pais/el-subsidio-por-tanque-de-gas-supera-los-13/

Gueddari-Aourir, A., García-Alaminos, A., García-Yuste, S., Alonso-Moreno, C., Canales-Vázquez, J., & Zafrilla, J. E. (2022). The carbon footprint balance of a real-case wine fermentation CO2 capture and utilization strategy. Renewable and Sustainable Energy Reviews, 157. https://doi.org/10.1016/j.rser.2021.112058

Mir, A., Tabar, M., & Fakhr, S. E. (2019). Greenhouse Gas Emission Estimation by Life Cycle Assessment Approach in Petrochemical Industry. https://www.researchgate.net/publication/337227174

Edwards, R., O’Connell, A., Padella, M., Giuntoli, J., Koeble, R., Bulgheroni, C., Marelli, L., & Lonza, L. (2019). Definition of input data to assess GHG default emissions from biofuels in EU legislation. https://doi.org/10.2760/69179

Peng, P., Lan, Y., Liang, L., & Jia, K. (2021). Membranes for bioethanol production by pervaporation. Biotechnology for Biofuels, 14(1), 1–33. https://doi.org/10.1186/s13068-020-01857-y

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Copyright (c) 2023 Devi Orozco, Ana Velastegui, Nicolas Vela-Garcia