Vol. 2 Núm. 2 (2010), SECCIÓN A: CIENCIAS EXACTAS
Vol. 2 Núm. 2 (2010)

Síntesis de 2,8,14,20-tetra-n-butilpirogalol[4]areno y estudio computacional conformacional

SECCIÓN A: CIENCIAS EXACTAS
Publicado 2010-06-01
Cesar H. Zambrano
Universidad San Francisco de Quito
Carlos A. Manzano
Universidad San Francisco de Quito
Andrea S. Saltos
Universidad San Francisco de Quito
Eric E. Dueno
Bainbridge University
Matthew Zeller
Youngstown State University
Portada Avances en Ciencias e Ingenierías Volumen 2 - Número 2 2010

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Palabras clave

pirogalolareno
butil
rayos-X
cálculos semiempíricos
conformación

Cómo citar

Zambrano, C. H., Manzano, C. A., Saltos, A. S., Dueno, E. E., & Zeller, M. (2010). Síntesis de 2,8,14,20-tetra-n-butilpirogalol[4]areno y estudio computacional conformacional. ACI Avances En Ciencias E Ingenierías, 2(2). https://doi.org/10.18272/aci.v2i2.22
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Resumen

Este trabajo presenta la obtención de aluminosilicatos mesoporosos generados mediante condensación de xerogel a partir de alcóxido de silicio (TEOS) y precursores de aluminio de diversas fuentes. Se usaron nitrato de aluminio (NAN), como fuente inorgánica y el alcoxido, tris-sec-butilato de aluminio (TBA) como fuente órgano-metálica. Se analizó la importancia del tamaño de cadena de alquilo en el surfactante (Tritón-X) en el proceso de condensación de la red, y su posterior influencia sobre el área superficial y en la obtención de mesoporos en los materiales. Adicionalmente se estudió la influencia de las variables mencionadas sobre la estabilidad hidrotermal de los aluminosilicatos.

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