Abstract
Orange peel is an abundant organic waste in Ecuador that can be used and transformed into products of high added value. Therefore, this work analyzes the technical-economic pre-feasibility of a biorefinery from orange peel to obtain essential oil, pectin and / or bioethanol. First, several scenarios were compared around the combination of products to be obtained, and it was established that the most convenient one would be obtaining essential oil and pectin, with an annual production of 8.7 and 44.4 tons, respectively. Next, a process was designed for this biorefinery that consists of 3 sections: the pretreatment of raw material, extraction of the oil, and the extraction of pectin. Material and energy balances of the process were carried out, and later, the equipment was selected and sized according to specific methodologies. The process considered the recovery and recirculation of ethanol used in the pectin extraction section to reduce production costs. Finally, an economic analysis was carried out based on the theoretical cost estimates and a catalog cost analysis. It was found that the project is profitable, and that the payback time for the investment would be between 5 and 6 years. Therefore, the implementation of the biorefinery would generate a positive economic, environmental and social impact in the country.
References
Shahbandeh, M. (2020). Orange production worldwide from 2012/2013 to 2019/2020. Recuperado de: https://www.statista.com/statistics/577398/world-Orange-production/#statisticContainer
INEC. (2016). Encuesta de Superficie y Producción Agropecuaria Continua.
Favela-Hernandez, J. M. J., Gonzalez-Santiago, O., Ramirez-Cabrera, M. A., Esquivel-Femno, P. C., & CamachoCorona, M. D. R. (2016). Chemistry and pharmacology of Citrus sinensis. Molecules, 21(2). doi: https://doi.org/10.3390/molecules21020247
Ulloa, C., & Almeida, D. (2012). Estudio de las Opciones de Reutilización Energética o Material de Cáscaras de Naranja (Tesis de Grado). Universidad San Francisco de Quito. Recuperado de: https://repositorio.usfq.edu.ec/bitstream/23000/6983/1/136137.pdf
Ortiz-Sanchez, M., Solarte-Toro, J. C., Orrego-Alzate, C. ., Acosta-Medina, C. ., & Cardona-Alzate, C. . (2019). Integral use of orange peel waste through the biorefinery concept: an experimental, technical, energy, and economic assessment. Biomass Conversion and Biorefinery. doi: https://doi.org/10.1007/s13399-020-00627-y
De la Torre, I., Martin-Dominguez, V., Acedos, M. G., Esteban, J., Santos, V. E., & Ladero, M. (2019). Utilisation/upgrading of orange peel waste from a biological biorefinery perspective. Applied Microbiology and Biotechnology,103(15), 5975-5991. doi: https://doi.org/10.1007/s00253-019-09929-2
Siles, J., Li, Q., & Thompson, I. (2010). Biorefinery of waste orange peel. Critical Reviews in Biotechnology, 30(1),6369. doi: https://doi.org/10.3109/07388550903425201
Alvarado, T., & Hernández, A. (2018). Revisión de alternativas sostenibles para el aprovechamiento del orujo de naranja Resumen Introducción. Revista Colombiana de Investigaciones Agroindustriales, 5(2), 9-32. doi: https://doi.org/10.23850/24220582.1393
Peredo-Luna, H. A., Palou-García, E., & López-Malo, A. (2009). Aceites esenciales: métodos de extracción. Temas Selectos de Ingeniería de Alimentos, 3-1, 24-32.
Thakur, B. R., Singh, R. K., & Handa, A. K. (1997). Chemistry and Uses of Pectin - A Review. Critical Reviews in Food Science and Nutrition, 37(1), 47-73. doi: https://doi.org/10.1080/10408399709527767
Quintana, J., Pérez, J., & Young, H. (2011). Obtención De Etanol a Partir De Residuos De Poda, Mediante Hidrólisis Ácida E Hidrólisis Enzimática. Revista U.D.C.A Actualidad & Divulgación Científica, 14(1), 111-116.
SENAE. (2020). Importaciones. Recuperado de: https://www.aduana.gob.ec/importaciones/
Cadena, D., & Álvarez-Bareto, J. F. (2020). Diseño de una planta de producción de pectina a partir de granadilla(Passiflora ligularis) para aplicaciones en Biomateriales (Tesis de Grado). Universidad San Francisco de Quito.
Oberoi, H., Vadlani, P. V., Madl, R., Saida, L., & Abeykoon, J. (2010). Ethanol Production from Orange Peels: TwoStage Hydrolysis and Fermentation Studies Using Optimized Parameters through Experimental Design. J. Agric. Food Chem., 58(2010), 3422-3429. doi: https://doi.org/10.1021/jf903163t
Tejeda, L., Marimón, W., & Medina, M. (2014). Evaluación del potencial de las cáscaras de frutas en la obtención de bioetanol. Hechos Microbiológicos, 5(1), 4-9.
Montoya, M. I., Quintero, J. A., Sánchez, O. J., & Cardona, C. A. (2005). Evaluación económica del proceso de obtención de alcohol carburante a partir de caña de azúcar y maíz. Revista Universidad EAFIT, 41(139), 76-87.
Tigua, G., & Espinoza, R. (2013). Estudio de la Industria Azucarera y su Impacto en el Desarrollo Socio-Económico del Cantón Milagro (Tesis de Grado). Universidad Estatal de Milagro. Recuperado de: http://repositorio.unemi.edu.ec/handle/123456789/540
Granger, B., Smith, S., & Poppick, H. (2016). Column. Recuperado de: https://processdesign.mccormick.northwestern.edu/index.php/Column
Towler, G., & Sinnott, R. A. Y. (2008). Principles, Practice and Economics of Plant and Process Design. In Chemical Engineering Design. Elsevier. doi: https://doi.org/10.1016/b978-0-08-096659-5.00022-5
Shawabkeh, R. (2007). Steps for design of Furnace/Fired Heater. King Fahd University of Petroleum & Minerals, September. doi: https://doi.org/10.13140/RG.2.1.4304.3049
Koretsky, M. (2013). Engineering and Chemical Thermodynamics (2da Edicio). Nueva Jersey: Wiley.
Geankoplis, C. J. (1998). Procesos de Transporte y Operaciones Unitarias (3era Edici). Mexico: CECSA.

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